Discovery of “Magic” Chemical That Makes Perfect Edges in 2D-Materials

Ultra-thin materials like Graph promise a revolution in nanoscience and technology. Researchers at Chalmers University of TechnologySweden has now made important progress in this area. In a recent article in Communication with nature They present a method of controlling the edges of two-dimensional materials using a “magic” chemical.

“Our method makes it possible to control the edges – atom by atoms – in a way that is both simple and scalable, using only mild warming along with abundant environmentally friendly chemicals like hydrogen peroxide, ”says Battulga Munkhbat, postdoctoral fellow at the Department of Physics at Chalmers University of Technology and lead author of the paper.

Materials that are as thin as a single layer of atoms are known as two-dimensional or 2D materials. The best-known example is graphene and molybdenum disulfide, its semiconductor analog. Future developments in this area could benefit from studying one particular feature that is inherent in such materials – their edges. Controlling the edges is a challenging scientific problem as they are very different from the main body of a 2D material. For example, a certain type of edge found in transition metal dichalcogenides (known as TMDs, such as the molybdenum disulfide mentioned above) can have magnetic and catalytic properties.

“Our method makes it possible to control the edges – atom by atom – in a simple and scalable way using only mild heating along with abundant environmentally friendly chemicals like hydrogen peroxide,” says Battulga Munkhbat, a postdoctoral fellow at Chalmers University’s Department of Physics of Technology and first author of the paper. Photo credit: Anna Lena Lundqvist / Chalmers University of Technology

Typical TMD materials have edges that can come in two different flavors known as zigzags or armchairs. These alternatives are so different that their physical and chemical properties are not the same at all. For example, calculations predict that zigzag edges are metallic and ferromagnetic, while chair edges are semi-conductive and non-magnetic. Similar to these remarkable variations in physical properties, one might expect the chemical properties of zigzag and chair edges to be very different as well. In this case, it is possible that certain chemicals “dissolve” the edges of the armchair and the zigzag remains untouched.

One such “magic” chemical is exactly what the Chalmers researchers found – in the form of ordinary hydrogen peroxide. The researchers were initially completely surprised by the new results.

“This method opens up new and unprecedented possibilities for Van der Waals materials (layered 2D materials). We can now combine edge physics with 2D physics in a single material. It’s an extremely fascinating development, ”says Timur Shegai, associate professor in the Physics Department in Chalmers and head of the research project. Photo credit: Anna Lena Lundqvist / Chalmers University of Technology

“It was not only that one type of edge dominated the other, but also that the resulting edges were extremely sharp – almost atomically sharp. This indicates that the “magic” chemical is working in what is called a self-limiting way, removing unwanted material atom by atom, ultimately leading to edges at the atomically sharp boundary. The resulting patterns followed the crystallographic orientation of the original TMD material and produced beautiful, atomically sharp hexagonal nanostructures, ”says Battulga Munkhbat.

“An extremely fascinating development”

The new process, which comprises a combination of standard top-down lithography processes with a new anisotropic wet etching process, therefore makes it possible to create perfect edges in two-dimensional materials.

“This method opens up new and unprecedented possibilities for Van der Waals materials (layered 2D materials). We can now combine edge physics with 2D physics in a single material. It’s an extremely fascinating development, ”says Timur Shegai, associate professor in the Physics Department in Chalmers and head of the research project.

These and other related materials often attract significant research attention as they enable critical advances in nanosciences and technologies. The potential applications range from quantum electronics to new types of nanodevices. These hopes are manifested in the graphene flagship, Europe’s largest research initiative of all time, coordinated by Chalmers University of Technology.

In order to make the new technology available to research laboratories and high-tech companies, the researchers founded a start-up company that offers high-quality atomically sharp TMD materials. The researchers also plan to further develop applications for these atomically sharp metamaterials.

Reference: “Transition Metal Dichalcogenide Metamaterials with Atomic Precision” by Battulga Munkhbat, Andrew B. Yankovich, Denis G. Baranov, Ruggero Verre, Eva Olsson and Timur O. Shegai, September 14, 2020, Communication with nature.
DOI: 10.1038 / s41467-020-18428-2